I expect he means the wall is clad in uPVC, common on modern homes (built in the last 30) years. Helps to cover up the fact they put the Work Experience boy (or girl) in charge of the brick (or block)work.
You can still put an outside tap though it, though given the choice, I would try find some masonry to fix it to.
As for plumbing, best to avoid the self cutting kits, they are not bad but you are essential cutting a hole in the side of watermain, no way of knowing how long those self cutting taps will last and they are more tricky to replace.
Polyplumb or easy-fit plastic fittings are the way to go, unless you have good soldering skills.
Then the barrier pipe can be taken right into the outdoor taps compression fitting, insert, olive and some petroleum jelly to seal it.
This works best if the pipe you are supply from is copper, although it is also plastic its not too difficult. Definitely after the stop valve and give the branch to the outside tap its own stop valve to turn off in October as well.