No it's not the same - my sulphur chips were made by Chempak, and don't seem to be widely available in shops, although I did manage to buy mine from a local garden centre rather than online.
They take a long time to break down and take effect, which isn't necessarily a bad thing.
Ammonium sulphate will actually lower the pH too, although it's generally used as a high nitrogen fertiliser. Being highly soluble the effect on pH is likely to be relatively short-lived.
Impossible to know whether your pH probe is giving you accurate results, but as Subversive Plot suggests, the odds are it isn't. A chemical (indicator dye) pH soil test kit is a much better bet.